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First Year Chemistry ThermoChemistry


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Q.1Selectthesuitableanswerfromthegivenchoices.(iv)Thechangeinheatenergyofachemicalreactionatconstanttemperatureandpressureiscalled:(a)enthalpychange(c)heatofsublimation(b)bondenergy(d)internalenergychangeQ.1 Select the suitable answer from the given choices.(iv) The change in heat energy of a chemical reaction at constant temperature and pressure is called:(a) enthalpy change(c) heat of sublimation(b) bondenergy(d) internal energy change

Q.5(a) Differentiate between the following:(i) Internal energy and enthalpy
Q.5(a) Differentiate between the following:(i) Internal energy and enthalpy

Q.5(a)Differentiatebetweenthefollowing:(i)InternalenergyandenthalpyQ.5(a) Differentiate between the following:(i) Internal energy and enthalpy

Q.4. Define the following terms and give three examples of each(v) Exothermic reaction
Q.4. Define the following terms and give three examples of each(v) Exothermic reaction

Q.4.Definethefollowingtermsandgivethreeexamplesofeach(v)ExothermicreactionQ.4. Define the following terms and give three examples of each(v) Exothermic reaction

Q.4. Define the following terms and give three examples of each(viii) Enthalpy of the system
Q.4. Define the following terms and give three examples of each(viii) Enthalpy of the system

Q.4.Definethefollowingtermsandgivethreeexamplesofeach(viii)EnthalpyofthesystemQ.4. Define the following terms and give three examples of each(viii) Enthalpy of the system

(b) How do you measure the heat of combustion of a substance by bomb calorimeter.
(b) How do you measure the heat of combustion of a substance by bomb calorimeter.

(b)Howdoyoumeasuretheheatofcombustionofasubstancebybombcalorimeter.(b) How do you measure the heat of combustion of a substance by bomb calorimeter.

Q.4. Define the following terms and give three examples of each(ii) Surroundings
Q.4. Define the following terms and give three examples of each(ii) Surroundings

Q.4.Definethefollowingtermsandgivethreeexamplesofeach(ii)SurroundingsQ.4. Define the following terms and give three examples of each(ii) Surroundings

Q.20 What is the meaning of the term enthalpy of ionization? If the heat of neutralization of \mathrm{HCl} and \mathrm{NaOH} is -57.3 \mathrm{~kJ} \mathrm{~mol}^{-1} and heat of neutralization of \mathrm{CH}_{3} \mathrm{COOH} with \mathrm{NaOH} is -55.2 \mathrm{~kJ} \mathrm{~mol}^{-1} calculate the enthalpy of ionization of \mathrm{CH}_{3} \mathrm{COOH} .(Ans: 2.1 \mathrm{~kJ} \mathrm{~mol}^{-1} )
Q.20 What is the meaning of the term enthalpy of ionization? If the heat of neutralization of  \mathrm{HCl}  and  \mathrm{NaOH}  is  -57.3 \mathrm{~kJ} \mathrm{~mol}^{-1}  and heat of neutralization of  \mathrm{CH}_{3} \mathrm{COOH}  with  \mathrm{NaOH}  is  -55.2 \mathrm{~kJ} \mathrm{~mol}^{-1}  calculate the enthalpy of ionization of  \mathrm{CH}_{3} \mathrm{COOH} .(Ans:  2.1 \mathrm{~kJ} \mathrm{~mol}^{-1}  )

Q.20Whatisthemeaningofthetermenthalpyofionization?IftheheatofneutralizationofHClandNaOHis57.3 kJ mol1andheatofneutralizationofCH3COOHwithNaOHis55.2 kJ mol1calculatetheenthalpyofionizationofCH3COOH.(Ans:2.1 kJ mol1)Q.20 What is the meaning of the term enthalpy of ionization? If the heat of neutralization of \mathrm{HCl} and \mathrm{NaOH} is -57.3 \mathrm{~kJ} \mathrm{~mol}^{-1} and heat of neutralization of \mathrm{CH}_{3} \mathrm{COOH} with \mathrm{NaOH} is -55.2 \mathrm{~kJ} \mathrm{~mol}^{-1} calculate the enthalpy of ionization of \mathrm{CH}_{3} \mathrm{COOH} .(Ans: 2.1 \mathrm{~kJ} \mathrm{~mol}^{-1} )

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