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Electrochemistry

Oxidation

Chemistry

Oxidation:

Oxidation is a chemical process that involves the loss of electrons, an increase in oxidation number, loss of hydrogen atoms, and gain of oxygen atoms in a substance.

Loss of Electrons

When a substance loses electrons during a chemical reaction, it is said to undergo oxidation. This occurs when the substance is oxidized, and its oxidation number increases.

Example: In the reaction , magnesium undergoes oxidation because it loses two electrons.

Equation: Mg → Mg2+^{2+} + 2e-

Increase in Oxidation Number

Oxidation is also defined as an increase in the oxidation number of a chemical species. The oxidation number is a measure of the number of electrons that an atom has gained or lost in a compound. When an atom loses electrons, its oxidation number increases, and it undergoes oxidation.

Example: In the reaction between hydrogen and chlorine to form hydrogen chloride, hydrogen undergoes oxidation because its oxidation number increases from 0 to +1.

Equation: H2_20^0 + Cl2_2 → 2H+1^{+1} Cl

Loss of Hydrogen Atom

Oxidation can also refer to the loss of hydrogen atoms in a chemical reaction. This is because hydrogen atoms carry a positive charge, and their loss leads to the oxidation of the substance.

Example: In the reaction between methane and oxygen to form carbon dioxide and water, methane undergoes oxidation because it loses four hydrogen atoms.

Equation: CH4_4 + 2O2_2 → CO2_2 + 2H2_2O (Combustion of methane)

Gain of Oxygen Atom

Oxidation can also refer to the gain of oxygen atoms in a substance during a chemical reaction. Oxygen atoms carry a negative charge, and their addition to a substance leads to the oxidation of that substance.

Example: In the reaction between sulfur di oxide and oxygen to form sulfur trioxide, sulfur di oxide undergoes oxidation because it gains oxygen atoms.

Equation: 2SO2_2 + O2_2 → 2SO3_3