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Electrochemistry

Reduction

Chemistry

Reduction:

Reduction is a chemical process that involves the gain of electrons, a decrease in oxidation number, gain of hydrogen atoms, and loss of oxygen atoms in a substance.

Gain of Electrons

When a substance gains electrons during a chemical reaction, it is said to undergo reduction. This occurs when the substance is reduced, and its oxidation number decreases.

Example: In the reaction, chlorine undergoes reduction because it gains an electron.

Equation: Cl2_2 + 2e- → 2Cl1^{-1}

Decrease in Oxidation Number

Reduction is also defined as a decrease in the oxidation number of a chemical species. The oxidation number is a measure of the number of electrons that an atom has gained or lost in a compound. When an atom gains electrons, its oxidation number decreases, and it undergoes reduction.

Example: In the reaction between copper oxide and hydrogen gas to form copper metal and water, copper undergoes reduction because its oxidation number decreases from +2 to 0.

Equation: Cu+2^{+2}O + H2_2 → Cu0^0 + H2_2O

Gain of Hydrogen Atom

Reduction can also refer to the gain of hydrogen atoms in a chemical reaction. This is because hydrogen atoms carry a positive charge, and their addition leads to the reduction of the substance.

Example: In the reaction between nitrogen and hydrogen to form ammonia, nitrogen undergoes reduction because it gains three hydrogen atoms.

Equation: N2_2 + 3H2_2 → 2NH3_3

Loss of Oxygen Atom

Reduction can also refer to the loss of oxygen atoms in a substance during a chemical reaction. Oxygen atoms carry a negative charge, and their loss leads to the reduction of that substance.

Example: In the reaction between iron oxide and aluminum, iron oxide undergoes reduction because it loses oxygen atoms.

Equation: Fe2_2O3_3 + 2 Al → Al2_2O3_3 + 2 Fe